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Scientific paper - Original scientific paper
Vibrationally resolved N 1s absorption spectra of the acrylonitrile molecule
Physical Review A, 85 (2012), 6; 062521. https://doi.org/10.1103/PhysRevA.85.062521
Ilakovac, Vita; Houari, Ymene; Carniato, Stephane; Gallet, Jean-Jacques; Kukk, Edwin; Horvatić, Davor

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Ilakovac, V., Houari, Y., Carniato, S., Gallet, J. J., Kukk, E. & Horvatić, D. (2012). Vibrationally resolved N 1s absorption spectra of the acrylonitrile molecule. Physical Review A, 85. (6). doi: 10.1103/PhysRevA.85.062521

Ilakovac, Vita, et al. "Vibrationally resolved N 1s absorption spectra of the acrylonitrile molecule." Physical Review A, vol. 85, no. 6, 2012. https://doi.org/10.1103/PhysRevA.85.062521

Ilakovac, Vita, Ymene Houari, Stephane Carniato, Jean Jacques Gallet, Edwin Kukk and Davor Horvatić. "Vibrationally resolved N 1s absorption spectra of the acrylonitrile molecule." Physical Review A 85, no. 6 (2012). https://doi.org/10.1103/PhysRevA.85.062521

Ilakovac, V., et al. (2012) 'Vibrationally resolved N 1s absorption spectra of the acrylonitrile molecule', Physical Review A, 85(6). doi: 10.1103/PhysRevA.85.062521

Ilakovac V, Houari Y, Carniato S, Gallet JJ, Kukk E, Horvatić D. Vibrationally resolved N 1s absorption spectra of the acrylonitrile molecule. Physical Review A [Internet]. 2012 [cited 2024 November 30];85(6). doi: 10.1103/PhysRevA.85.062521

V. Ilakovac, Y. Houari, S. Carniato, J. J. Gallet, E. Kukk and D. Horvatić, "Vibrationally resolved N 1s absorption spectra of the acrylonitrile molecule", Physical Review A, vol. 85, no. 6, 2012. [Online]. Available at: https://urn.nsk.hr/urn:nbn:hr:217:253815. [Accessed: 30 November 2024]

Metadata
Title (english)Vibrationally resolved N 1s absorption spectra of the acrylonitrile molecule
AuthorVita Ilakovac
AuthorYmene Houari
AuthorStephane Carniato
AuthorJean-Jacques Gallet
AuthorEdwin Kukk
AuthorDavor Horvatić
Author's institutionUniversity of Zagreb
Faculty of Science
(Department of Physics)
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Physics
Abstract (english)
Besides two strong π∗⊥1 and π∗∥ resonances in the 398- to 400-eV energy range, N 1s near edge x-ray absorption fine structure spectra of acrylonitrile molecules have a less intense 401- to 403-eV doublet. The two components correspond to the N 1s → π∗⊥2 and N 1s → D∗∥ transitions, where D∗∥ is a diffuse state with strong Rydberg character. The vibrational analysis shows that in the D∗∥ excited state, two low-energy out-of-plane normal modes are strongly excited. The π∗⊥2 excitation triggers a set of in-plane vibrations, in particular, two C=C–C≡N bendings of the molecule.
Languageenglish
Publication typeScientific paper - Original scientific paper
Publication statusPublished
Peer reviewPeer review - international
Publication versionPublished version
Journal titlePhysical Review A
Numberingvol. 85, no. 6, 062521
p-ISSN1050-2947
DOIhttps://doi.org/10.1103/PhysRevA.85.062521
URN:NBNurn:nbn:hr:217:253815
Publication2012
Document URLhttp://link.aps.org/doi/10.1103/PhysRevA.85.062521
Type of resourceText
Access conditionsOpen access
Terms of useLicence In copyright icon
Public noteCopyright (2012) by the American Physical Society. Received 26 April 2012; published 29 June 2012.
Created on2019-11-16 17:57:41