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doctoral thesis
Mechanochemical synthesis and structural characterization of bimetallic and hybrid tetrahydridoborates
Zagreb: University of Zagreb, Faculty of Science, 2019. urn:nbn:hr:217:131290
Burazer, Sanja
University of Zagreb
Faculty of Science
Department of Chemistry

Institutional repository: Repository of the Faculty of Science

Cite this document

Burazer, S. (2019). Mechanochemical synthesis and structural characterization of bimetallic and hybrid tetrahydridoborates (Doctoral thesis). Zagreb: University of Zagreb, Faculty of Science. Retrieved from https://urn.nsk.hr/urn:nbn:hr:217:131290

Burazer, Sanja. "Mechanochemical synthesis and structural characterization of bimetallic and hybrid tetrahydridoborates." Doctoral thesis, University of Zagreb, Faculty of Science, 2019. https://urn.nsk.hr/urn:nbn:hr:217:131290

Burazer, Sanja. "Mechanochemical synthesis and structural characterization of bimetallic and hybrid tetrahydridoborates." Doctoral thesis, University of Zagreb, Faculty of Science, 2019. https://urn.nsk.hr/urn:nbn:hr:217:131290

Burazer, S. (2019). 'Mechanochemical synthesis and structural characterization of bimetallic and hybrid tetrahydridoborates', Doctoral thesis, University of Zagreb, Faculty of Science, accessed 31 December 2024, https://urn.nsk.hr/urn:nbn:hr:217:131290

Burazer S. Mechanochemical synthesis and structural characterization of bimetallic and hybrid tetrahydridoborates [Doctoral thesis]. Zagreb: University of Zagreb, Faculty of Science; 2019 [cited 2024 December 31] Available at: https://urn.nsk.hr/urn:nbn:hr:217:131290

S. Burazer, "Mechanochemical synthesis and structural characterization of bimetallic and hybrid tetrahydridoborates", Doctoral thesis, University of Zagreb, Faculty of Science, Zagreb, 2019. Available at: https://urn.nsk.hr/urn:nbn:hr:217:131290

Metadata
TitleMechanochemical synthesis and structural characterization of bimetallic and hybrid tetrahydridoborates
Title (croatian)Mehanokemijska sinteza i strukturna karakterizacija dimetalnih i hibridnih tetrahidridoborata
AuthorSanja Burazer
MentorJasminka Popović (mentor)
Committee memberVladimir Stilinović (predsjednik povjerenstva)
Committee memberMarijana Jurić (član povjerenstva)
Committee memberDubravka Matković-Čalogović (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Science
(Department of Chemistry)
Zagreb
Defense date and country2019-10-18, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Universal decimal classification
(UDC)		54 - Chemistry. Crystallography. Mineralogy
Abstract
Mechanochemical reactions of metal tetrahydridoborates and metal imidazolates, as well as the structural characteristics of the obtained products were investigated. X-ray powder diffraction, both at the laboratory diffractometer and in-situ high-temperature diffraction under the synchrotron radiation was mainly used experimental technique. NMR was used as a complementary technique. Combination of molecular building blocks of lithium borohydride, LiBH4, and lithium imidazolate, LiIm, led to the formation of hybrid Li2ImBH4 with a high conversion rate. New compounds containing alkali and alkaline earth metal centers, AMgIm3 (A = Na, K), were found. New compounds of manganese imidazolates with alkaline metal centers were prepared, AMnIm3 (A = Na, K). Crystal structure determination of the new compounds was carried out from the powder diffraction data using methods in the direct space. New methods of preparation of crystalline magnesium imidazolate, MgIm2, and high-temperature polymorph of sodium imidazolate, HT-NaIm, are described. Structure of HT-NaIm was determined from the single crystal diffraction data.
Abstract (croatian)
Istražene su mehanokemijske reakcije metalnih tetrahidridoborata i metalnih imidazolata te strukturne značajke dobivenih produkata. Rendgenska difrakcija u polikristalu na laboratorijskom difraktometru te in-situ visokotemperaturna difrakcija na sinkrotronskoj liniji najvažnije su eksperimentalne tehnike korištene u ovom radu, a neki uzorci dodatno su okarakterizirani pomoću nuklearne magnetske rezonancije u čvrstom stanju. Poboljšan je sintetski put priprave hibridne metalohidridne organske mreže, Li2ImBH4, nastale kombinacijom molekulskih građevnih blokova litijevog borohidrida, LiBH4, i litijevog imidazolata, LiIm, uz visok stupanj konverzije. Otkrivena je nova skupina dimetalnih magnezijevih imidazolata, prvih imidazolatnih spojeva koji sadrže alkalijske i zemnoalkalijske metalne centre, AMgIm3 (A = Na, K). Priređeni su novi dimetalni spojevi manganovog imidazolata s alkalijskim metalnim centrima, AMnIm3 (A = Na, K). Određivanje struktura novih spojeva provedeno je iz difrakcijskh podataka polikristalnih uzoraka pomoću metoda u direktnom prostoru. Otkriven je nov način pripreme kristalnog magnezijevog imidazolata, MgIm2, te visokotemperaturnog (HT) polimorfa natrijevog imidazolata, HT-NaIm, čija struktura je određena iz difrakcijskih podataka jediničnog kristala
Keywords
Keywords (croatian)
Languageenglish
URN:NBNurn:nbn:hr:217:131290
Study programmeTitle: Doctoral study in chemistry
Study programme type: university
Study level: postgraduate
Academic / professional title: doktor/doktorica znanosti, područje prirodnih znanosti, polje kemija (doktor/doktorica znanosti, područje prirodnih znanosti, polje kemija)
Type of resourceText
Extent163 str. ; 30 cm
File originBorn digital
Access conditionsOpen access
Embargo expiration date: 2021-04-19
Terms of useLicence In copyright icon
Created on2019-12-04 14:20:31