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master's thesis
Synthesis and catalytic activity of novel molybdenum hydrazonato complexes
Zagreb: University of Zagreb, Faculty of Science, 2019. urn:nbn:hr:217:563316
Razum, Marta
University of Zagreb
Faculty of Science
Department of Chemistry

Institutional repository: Repository of the Faculty of Science

Cite this document

Razum, M. (2019). Synthesis and catalytic activity of novel molybdenum hydrazonato complexes (Master's thesis). Zagreb: University of Zagreb, Faculty of Science. Retrieved from https://urn.nsk.hr/urn:nbn:hr:217:563316

Razum, Marta. "Synthesis and catalytic activity of novel molybdenum hydrazonato complexes." Master's thesis, University of Zagreb, Faculty of Science, 2019. https://urn.nsk.hr/urn:nbn:hr:217:563316

Razum, Marta. "Synthesis and catalytic activity of novel molybdenum hydrazonato complexes." Master's thesis, University of Zagreb, Faculty of Science, 2019. https://urn.nsk.hr/urn:nbn:hr:217:563316

Razum, M. (2019). 'Synthesis and catalytic activity of novel molybdenum hydrazonato complexes', Master's thesis, University of Zagreb, Faculty of Science, accessed 18 May 2024, https://urn.nsk.hr/urn:nbn:hr:217:563316

Razum M. Synthesis and catalytic activity of novel molybdenum hydrazonato complexes [Master's thesis]. Zagreb: University of Zagreb, Faculty of Science; 2019 [cited 2024 May 18] Available at: https://urn.nsk.hr/urn:nbn:hr:217:563316

M. Razum, "Synthesis and catalytic activity of novel molybdenum hydrazonato complexes", Master's thesis, University of Zagreb, Faculty of Science, Zagreb, 2019. Available at: https://urn.nsk.hr/urn:nbn:hr:217:563316

Metadata
TitleSynthesis and catalytic activity of novel molybdenum hydrazonato complexes
Title (croatian)Sinteza i katalitička aktivnost hidrazonskih kompleksa molibdena
AuthorMarta Razum
MentorJana Pisk (mentor)
MentorDominique Agustin https://orcid.org/0000-0003-1933-8442 (mentor)
Committee memberJana Pisk (predsjednik povjerenstva)
Committee memberIva Juranović Cindrić (član povjerenstva)
Committee memberIvana Biljan (član povjerenstva)
Committee memberVišnja Vrdoljak (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Science
(Department of Chemistry)
Zagreb
Defense date and country2019-11-14, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
As part of this diploma thesis, solution-based and mechanochemical syntheses of hydrazone compounds, obtained from 2,3-dihydroxybenzaldehyde and 2- or 4-aminobenzhydrazide (H2L1 and H2L2), was performed. Two dinuclear dioxomolybdenum(VI) complexes, [MoO2L]2, and two mononuclear complexes, [MoO2L(MeOH),] have been synthesised by the reaction of [MoO2(acac)2] and corresponding hydrazone ligand H2L in 1:1 molar ratio. Mononuclear complexes [MoO2L(MeOH)] were obtained from methanol solution, while dinuclear complexes [MoO2L]2 from acetonitrile one. Complexes were characterised by IR and NMR spectroscopies and analysed by TG and elemental analyses. The catalytic activity of all complexes was tested under organic solvent-free for the epoxidation of cis-cyclooctene and oct-1-ene with three different oxidants, aqueous tert-butyl hydroperoxide, tert-butyl hydroperoxide in decane and hydrogen peroxide, with the emphasis on the low catalyst loading (0.25 mol% vs. substrate).
Abstract (croatian)
U sklopu ovog diplomskog rada izvedene su otopinske i mehanokemijske sinteze hidrazonskih spojeva, priređenih iz 2,3-dihidroksibenzaldehida i 2- ili 4-aminobenzhidrazida (H2L1 i H2L2). Dva dinuklearna kompleksa dioksomolibdena(VI), [MoO2L]2 i dva mononuklearna kompleksa [MoO2L(MeOH)] sintetizirani su reakcijom [MoO2(acac)2] i odgovarajućeg hidrazonskog liganda H2L u molarnom omjeru 1:1. Mononuklearni kompleksi [MoO2L(MeOH)] dobiveni su iz otopine metanola, dok dinuklearni kompleksi [MoO2L]2 iz acetonitrila. Kompleksi su karakterizirani IR i NMR spektroskopijom i analizirani TG i elementarnim analizama. Katalitička aktivnost svih kompleksa ispitana je epoksidacijom cis-ciklooktena i okt-1-ena bez dodatka organskih otapala u reakcijski medij, s tri različita oksidansa, vodenom otopinom tert-butil hidroperoksida, tert-butil hidroperoksidom u dekanu i vodikovim peroksidom, s naglaskom na mali udio katalizatora (0,25 mol.% u odnosu na supstrat).
Keywords
Keywords (croatian)
Languageenglish
URN:NBNurn:nbn:hr:217:563316
Study programmeTitle: Graduate university studies in chemistry; specializations in: Research programme
Course: Research programme
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra kemije (magistar/magistra kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Embargo expiration date: 2021-11-14
Terms of useLicence In copyright icon
Created on2019-12-11 13:03:22