prikaz prve stranice dokumenta Synthesis and application of molybdenum based catalyst for oxidation reactions
  Download
PDF 3.5 MB
master's thesis
Synthesis and application of molybdenum based catalyst for oxidation reactions
Zagreb: University of Zagreb, Faculty of Science, 2019. urn:nbn:hr:217:391184
Mihalinec, Josipa
University of Zagreb
Faculty of Science
Department of Chemistry

Institutional repository: Repository of the Faculty of Science

Cite this document

Mihalinec, J. (2019). Synthesis and application of molybdenum based catalyst for oxidation reactions (Master's thesis). Zagreb: University of Zagreb, Faculty of Science. Retrieved from https://urn.nsk.hr/urn:nbn:hr:217:391184

Mihalinec, Josipa. "Synthesis and application of molybdenum based catalyst for oxidation reactions." Master's thesis, University of Zagreb, Faculty of Science, 2019. https://urn.nsk.hr/urn:nbn:hr:217:391184

Mihalinec, Josipa. "Synthesis and application of molybdenum based catalyst for oxidation reactions." Master's thesis, University of Zagreb, Faculty of Science, 2019. https://urn.nsk.hr/urn:nbn:hr:217:391184

Mihalinec, J. (2019). 'Synthesis and application of molybdenum based catalyst for oxidation reactions', Master's thesis, University of Zagreb, Faculty of Science, accessed 08 May 2024, https://urn.nsk.hr/urn:nbn:hr:217:391184

Mihalinec J. Synthesis and application of molybdenum based catalyst for oxidation reactions [Master's thesis]. Zagreb: University of Zagreb, Faculty of Science; 2019 [cited 2024 May 08] Available at: https://urn.nsk.hr/urn:nbn:hr:217:391184

J. Mihalinec, "Synthesis and application of molybdenum based catalyst for oxidation reactions", Master's thesis, University of Zagreb, Faculty of Science, Zagreb, 2019. Available at: https://urn.nsk.hr/urn:nbn:hr:217:391184

Metadata
TitleSynthesis and application of molybdenum based catalyst for oxidation reactions
Title (croatian)Priprava kompleksnih spojeva molibdena i njihova primjena kao katalizatora u reakcijama oksidacije
AuthorJosipa Mihalinec
MentorJana Pisk (mentor)
MentorPascal Guillo https://orcid.org/0000-0002-9818-7824 (mentor)
Committee memberJana Pisk (predsjednik povjerenstva)
Committee memberTajana Begović (član povjerenstva)
Committee memberIva Juranović Cindrić (član povjerenstva)
Committee memberVišnja Vrdoljak (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Science
(Department of Chemistry)
Zagreb
Defense date and country2019-11-12, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
Synthesis of the dioxomolybdenum(VI) was carried out by using [MoO2(acac)2] and the corresponding ONO hydrazone ligand (2,3-dihydroxbenzaldehyde isonicotinoylhydrazone, H2L1 or 2,3-dihydroxbenzaldehyde nicotinoylhydrazone, H2L2). Polynuclear complexes, [MoO2(L1)]n∙MeCN and [MoO2(L2)]n were obtained from acetonitrile, whereas mononuclear complexes [MoO2(L1,2)(MeOH)] were isolated from methanolic solution. The mechanochemical synthesis employing liquid assisted grinding was also applied, and H2L1 ligand and mononuclear complexes were obtained in such a way. Ex-situ powder X-ray diffraction method was implemented for monitoring H2L1 ligand obtained by mechanochemical synthesis. Complexes were characterized by IR spectroscopy, elemental and termogravimetric analysis. Additionally, polynuclear complexes were characterized by NMR spectroscopy. Molecular and crystal structures of H2L1 ligand and its mononuclear complex were determined by the single crystal X-ray diffraction. Lastly, the complexes were tested as catalyst in oxidation reactions of secondary alcohols, carveol and cyclohexanol by using H2O2 and TBHP (in aqueos solution or solution in decane).
Abstract (croatian)
U okviru ovog diplomskog rada pripravljeni su molibdenski(VI) kompleksi reakcijom [MoO2(acac)2] i odgovarajućeg hidrazonskog liganda (2,3-dihidroksibenzaldehid izonikotinhidrazona, H2L1 ili 2,3-dihidroksibenzaldehid nikotinhidrazona, H2L2). Izolirani su polinuklearni [MoO2(L1)]n∙MeCN i [MoO2(L2)]n iz acetonitrila i mononuklearni kompleksi [MoO2(L1,2)(MeOH)] iz metanola. Ligand H2L1 i mononuklearne komplekse bilo je moguće sintetizirati mehanokemijski, mljevenjem potpomognuto kapljevinom. Osim toga, mehanokemijska sinteza liganda H2L1 je popraćena ex-situ metodom rentgenske difrakcije na polikristalnom uzorku. Kompleksi su identificirani IR spektroskopijom, elementnom i termogravimetrijskom analizom. Polinuklearni kompleksi karakterizirani su NMR spektroskopijom. Difrakcijom rentgenskog zračenja na monokristalnom uzorku je odreĎena kristalna struktura H2L1 liganda te njegovog mononuklearnog kompleksa. Na kraju, pripravljeni kompleksi su ispitani kao katalizatori u reakcijama oksidacije sekundarnih alkohola, karveola i cikloheksanola u prisutnosti H2O2 i TBHP-a (u vodenoj otopini i otopini u dekanu).
Keywords
Keywords (croatian)
Languageenglish
URN:NBNurn:nbn:hr:217:391184
Study programmeTitle: Graduate university studies in chemistry; specializations in: Research programme
Course: Research programme
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra kemije (magistar/magistra kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Embargo expiration date: 2021-11-12
Terms of useLicence In copyright icon
Created on2019-12-16 14:15:07