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Scientific paper - Original scientific paper
Correlation between structural, physical and chemical properties of three new tetranuclear NiII clusters
New Journal of Chemistry, 40 (2016), 8; 6604-6614. https://doi.org/10.1039/C6NJ00287K
Cindrić, Marina; Pavlović, Gordana; Pajić, Damir; Zadro, Krešo; Dominik, Cinčić; Hrenar, Tomica; Lekšić, Edislav; Prieto, Ana Belen Pinar; Lazić, Predrag; Šišak Jung, Dubravka

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Cindrić, M., Pavlović, G., Pajić, D., Zadro, K., Dominik, C., Hrenar, T. ... Šišak Jung, D. (2016). Correlation between structural, physical and chemical properties of three new tetranuclear NiII clusters. New Journal of Chemistry, 40. (8), 6604-6614. doi: 10.1039/C6NJ00287K

Cindrić, Marina, et al. "Correlation between structural, physical and chemical properties of three new tetranuclear NiII clusters." New Journal of Chemistry, vol. 40, no. 8, 2016, pp. 6604-6614. https://doi.org/10.1039/C6NJ00287K

Cindrić, Marina, Gordana Pavlović, Damir Pajić, Krešo Zadro, Cinčić Dominik, Tomica Hrenar, Edislav Lekšić, Ana Belen Pinar Prieto, Predrag Lazić and Dubravka Šišak Jung. "Correlation between structural, physical and chemical properties of three new tetranuclear NiII clusters." New Journal of Chemistry 40, no. 8 (2016): 6604-6614. https://doi.org/10.1039/C6NJ00287K

Cindrić, M., et al. (2016) 'Correlation between structural, physical and chemical properties of three new tetranuclear NiII clusters', New Journal of Chemistry, 40(8), pp. 6604-6614. doi: 10.1039/C6NJ00287K

Cindrić M, Pavlović G, Pajić D, Zadro K, Dominik C, Hrenar T, and sur.. Correlation between structural, physical and chemical properties of three new tetranuclear NiII clusters. New Journal of Chemistry [Internet]. 2016 [cited 2024 May 18];40(8):6604-6614. doi: 10.1039/C6NJ00287K

M. Cindrić, et al., "Correlation between structural, physical and chemical properties of three new tetranuclear NiII clusters", New Journal of Chemistry, vol. 40, no. 8, pp. 6604-6614, 2016. [Online]. Available at: https://urn.nsk.hr/urn:nbn:hr:217:664710. [Accessed: 18 May 2024]

Metadata
Title (english)Correlation between structural, physical and chemical properties of three new tetranuclear NiII clusters
AuthorMarina Cindrić
AuthorGordana Pavlović
AuthorDamir Pajić
AuthorKrešo Zadro
AuthorCinčić Dominik
AuthorTomica Hrenar
AuthorEdislav Lekšić
AuthorAna Belen Pinar Prieto
AuthorPredrag Lazić
AuthorDubravka Šišak Jung
Author's institutionUniversity of Zagreb
Faculty of Science
(Department of Physics)
Author's institutionUniversity of Zagreb
Faculty of Science
(Department of Chemistry)
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Physics
Abstract (english)
Based on a new family of NiII cubane-like clusters, this work addresses current challenges in synthesis, analysis and dynamics of single-molecule-magnet (SMM) systems. Investigation of various synthetic routes and desorption-sorption processes yielded series of isomorphous compounds: [Ni4L4(CH3OH)4]·xsolv, [Ni4L4(CH3OH)4] and [Ni4L4]. In order to analyze these deceivingly simple materials, several analytical and quantum mechanical methods had to be used. This revealed materials with mixed lattice solvents, statistical disorder of the solvent, and disordered [Ni4L4] cores, what offered an insight into risks of the self-assembly process and interconversion dynamics of the investigated NiII family. These findings also allowed structural-magnetic relationships to be established, and the outcomes were exploited in two turns: in first, effect of the coordinated and lattice solvent on the magnetic properties was examined, and in second, magnetic properties were used to facilitate crystal structure determination.
Keywords (english)
Languageenglish
Publication typeScientific paper - Original scientific paper
Publication statusPublished
Peer reviewPeer review - international
Publication versionPublished version
Journal titleNew Journal of Chemistry
Numberingvol. 40, no. 8, pp. 6604-6614
p-ISSN1144-0546
e-ISSN1369-9261
DOIhttps://doi.org/10.1039/C6NJ00287K
URN:NBNurn:nbn:hr:217:664710
Publication2016
Document URLhttps://pubs.rsc.org/en/content/articlelanding/2016/NJ/C6NJ00287K
Type of resourceText
Access conditionsOpen access
Terms of useLicence Attribution 3.0 Unported (CC BY 3.0) icon
Public note© The Royal Society of Chemistry and the Centre National de la Recherche Scientifique. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Received on 27 Jan 2016. Accepted on 18 May 2016. Published on 31 May 2016.
Created on2020-02-07 16:38:47