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doctoral thesis
Utjecaj bočnog ogranka prirodnih aminokiselina na topologiju pakiranja koordinacijskih polimera bakra(II)
Zagreb: University of Zagreb, Faculty of Science, 2021. urn:nbn:hr:217:180160
Smokrović, Kristina
University of Zagreb
Faculty of Science
Department of Chemistry

Institutional repository: Repository of the Faculty of Science

Cite this document

Smokrović, K. (2021). Utjecaj bočnog ogranka prirodnih aminokiselina na topologiju pakiranja koordinacijskih polimera bakra(II) (Doctoral thesis). Zagreb: University of Zagreb, Faculty of Science. Retrieved from https://urn.nsk.hr/urn:nbn:hr:217:180160

Smokrović, Kristina. "Utjecaj bočnog ogranka prirodnih aminokiselina na topologiju pakiranja koordinacijskih polimera bakra(II)." Doctoral thesis, University of Zagreb, Faculty of Science, 2021. https://urn.nsk.hr/urn:nbn:hr:217:180160

Smokrović, Kristina. "Utjecaj bočnog ogranka prirodnih aminokiselina na topologiju pakiranja koordinacijskih polimera bakra(II)." Doctoral thesis, University of Zagreb, Faculty of Science, 2021. https://urn.nsk.hr/urn:nbn:hr:217:180160

Smokrović, K. (2021). 'Utjecaj bočnog ogranka prirodnih aminokiselina na topologiju pakiranja koordinacijskih polimera bakra(II)', Doctoral thesis, University of Zagreb, Faculty of Science, accessed 31 December 2024, https://urn.nsk.hr/urn:nbn:hr:217:180160

Smokrović K. Utjecaj bočnog ogranka prirodnih aminokiselina na topologiju pakiranja koordinacijskih polimera bakra(II) [Doctoral thesis]. Zagreb: University of Zagreb, Faculty of Science; 2021 [cited 2024 December 31] Available at: https://urn.nsk.hr/urn:nbn:hr:217:180160

K. Smokrović, "Utjecaj bočnog ogranka prirodnih aminokiselina na topologiju pakiranja koordinacijskih polimera bakra(II)", Doctoral thesis, University of Zagreb, Faculty of Science, Zagreb, 2021. Available at: https://urn.nsk.hr/urn:nbn:hr:217:180160

Metadata
TitleUtjecaj bočnog ogranka prirodnih aminokiselina na topologiju pakiranja koordinacijskih polimera bakra(II)
Title (english)Side-chain effect of natural amino-acids on packing topology of copper(II) coordination polymers
AuthorKristina Smokrović
MentorIvica Đilović (mentor)
Committee memberĐani Škalamera (predsjednik povjerenstva)
Committee memberVladimir Stilinović (član povjerenstva)
Committee memberKrešimir Molčanov (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Science
(Department of Chemistry)
Zagreb
Defense date and country2021-04-23, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Universal decimal classification
(UDC)		54 - Chemistry. Crystallography. Mineralogy
Abstract
Istražen je utjecaj boˇcnog ogranka aminokiselina na topologiju koordinacijskih polimera bakra(II) s aminokiselinama i 4,4’-bipiridinom. U provedbi eksperimenata korištene su sve proteinogene aminokiseline. Priređeno je i strukturno karakterizirano dvadeset različitih koordinacijskih polimera, jedan koordinacijski polimer s glicilglicinom i jedan diskretni kompleksni spoj s histidinom, te tri vrste koordinacijskih polimera koji sadrže samo bakrove(II) i nitratne ione, te 4,4’-bipiridin kao premošćujući ligand. Osim utjecaja strukture bočnog ogranka, prouˇcen je i utjecaj otapala na dimenzionalnost i topologiju priređenih spojeva. Svi spojevi su strukturno karakterizirani difrakcijom rentgenskog zračenja na jediničnom kristalu, difrakcijom rentgenskog zračenja na polikristalnom uzorku, termogravimetrijskom analizom te infracrvenom spektroskopijom uz prigušenu totalnu refleksiju.
Abstract (english)
The influence of the amino-acids side-chain on the topology of coordination polymers of copper(II) with selected amino-acids and 4,4’-bipyridine was investigated. All proteinogenic amino-acids were used in the experiments. Twenty different coordination polymers, one coordination polymer with glycylglycine and one discrete complex complex with histidine, and three types of coordination polymers containing only copper(II) and nitrate ions, and 4,4’-bipyridine as a bridging ligand were prepared and structurally characterized. In addition to the influence of the side-chain structure, solvent impact on the dimensionality and topology of the target compounds was also studied, as well as the counterion influence. The compounds were structurally characterized by single crystal X-ray diffraction and X-ray diffraction on a polycrystalline sample, thermogravimetric analysis, and attenuated total reflectance spectroscopy.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:217:180160
Promotion2021
ProjectNumber: IP-2014-09-4274
Title: Esencijalni metalni ioni u proteinima iz Heliobacter pylori i modelnim spojevima-struktura u funkcija/svojstvo
Title: Essential metal ions in Helicobacter pylori proteins and model complexes – structure and function/property
Acronym: ProtModStruct
Leader: Dubravka Matković-Čalogović
Jurisdiction: Croatia
Funder: HRZZ
Funding stream: IP
Study programmeTitle: Doctoral study in chemistry
Study programme type: university
Study level: postgraduate
Academic / professional title: doktor/doktorica znanosti, područje prirodnih znanosti, polje kemija (doktor/doktorica znanosti, područje prirodnih znanosti, polje kemija)
Type of resourceText
Extent128 str. ; 30 cm
File originBorn digital
Access conditionsOpen access
Embargo expiration date: 2023-04-23
Terms of useLicence In copyright icon
Created on2021-04-30 11:20:03