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master's thesis
Aromatski diamini kao akceptori halogenske veze
Zagreb: University of Zagreb, Faculty of Science, 2021. urn:nbn:hr:217:213715
Uran, Erik
University of Zagreb
Faculty of Science
Department of Chemistry

Institutional repository: Repository of the Faculty of Science

Cite this document

Uran, E. (2021). Aromatski diamini kao akceptori halogenske veze (Master's thesis). Zagreb: University of Zagreb, Faculty of Science. Retrieved from https://urn.nsk.hr/urn:nbn:hr:217:213715

Uran, Erik. "Aromatski diamini kao akceptori halogenske veze." Master's thesis, University of Zagreb, Faculty of Science, 2021. https://urn.nsk.hr/urn:nbn:hr:217:213715

Uran, Erik. "Aromatski diamini kao akceptori halogenske veze." Master's thesis, University of Zagreb, Faculty of Science, 2021. https://urn.nsk.hr/urn:nbn:hr:217:213715

Uran, E. (2021). 'Aromatski diamini kao akceptori halogenske veze', Master's thesis, University of Zagreb, Faculty of Science, accessed 20 November 2024, https://urn.nsk.hr/urn:nbn:hr:217:213715

Uran E. Aromatski diamini kao akceptori halogenske veze [Master's thesis]. Zagreb: University of Zagreb, Faculty of Science; 2021 [cited 2024 November 20] Available at: https://urn.nsk.hr/urn:nbn:hr:217:213715

E. Uran, "Aromatski diamini kao akceptori halogenske veze", Master's thesis, University of Zagreb, Faculty of Science, Zagreb, 2021. Available at: https://urn.nsk.hr/urn:nbn:hr:217:213715

Metadata
TitleAromatski diamini kao akceptori halogenske veze
Title (english)Aromatic diamines as halogen bond acceptors
AuthorErik Uran
MentorVladimir Stilinović (mentor)
Committee memberVladimir Stilinović (predsjednik povjerenstva)
Committee memberIvana Biljan (član povjerenstva)
Committee memberGordan Horvat (član povjerenstva)
Committee memberDominik Cinčić (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Science
(Department of Chemistry)
Zagreb
Defense date and country2021-07-02, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
U sklopu ovog diplomskog rada sintetizirani su kokristali aromatskih diamina, p-fenilendiamina, benzidina te o-tolidina s perfluoriranim aromatskim donorima, 1,4-dijodtetrafluorbenzenom, 1,3-dijodtetrafluorbenzenom te 1,3,5-trifluor-2,4,6-trijodbenzenom. Sinteza kokristala bila je provedena mehanokemijski te iz otopine. Spojevi koji su sintetizirani mehanokemijski izučeni su rentgenskom difrakcijom na polikristalnom uzorku, a kokristalima kojima je uspješno priređen jedinični kristal iz otopine određena je kristalna i molekulska struktura. U kokristalima kojima je bilo moguće odrediti kristalnu i molekulsku strukturu izučila su se svojstva primarne amino skupine kao akceptora halogenske veze te geometrijski parametri tih veza. Određeno je i koje su ostale interakcije prisutne u kristalnim strukturama sintetiziranih kokristala te kako se promjenom broja i položaja atoma joda u donorima halogenske veze, ali i promjenom molekula akceptora (po pitanju broja i supstituiranosti fenilnih prstena), može mijenjati struktura kokristala.
Abstract (english)
As a part of this master thesis, halogen-bonded cocrystals were prepared using three aromatic diamines, p-phenylenediamine, benzidine, o-tolidine and three perfluorinated halogen bond donors, 1,4-diiodotetrafluorobenzene, 1,3-diiodotetrafluorobenzene and 1,3,5-trifluoro-2,4,6-triiodobenzene. The cocrystals were synthetized via mechanochemical synthesis and from the solution. Mechanochemically obtained cocrystals were analyzed by X-ray powder diffraction, while single crystals of the cocrystal, which were obtained by solution crystallization, were analyzed by single crystal X-ray diffraction. The proclivity of amine group to form halogen bond with iodine atom was investigated, as were other noncovalent interactions present in the synthetized cocrystals. It was also investigated how the postion and number of iodine atoms, as well as the number and supstitution of phenyl rings influences crystal packing.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:217:213715
ProjectNumber: IP-2014-09-7367
Title: Kristalno inženjerstvo višekomponentinih metaloorganksih materijala povezanih halogenskom vezom: ususret supramolekulskom ugađanju strukture i svojstava
Title: Crystal engineering of multicomponent halogen bonded metal-organic materials: towards supramolecular control over structure and properties
Acronym: CrystEngMOM
Leader: Dominik Cinčić
Jurisdiction: Croatia
Funder: HRZZ
Funding stream: IP
ProjectNumber: IP-2019-04-1868
Title: Nove građevne jedinke u supramolekulskom dizajnu složenih višekomponentnih molekulskih kristala temeljenih na halogenskim vezama
Title: New building blocks for the supramolecular design of complex multi-component molecular crystals based on halogen bonds
Acronym: HaloBond
Leader: Dominik Cinčić
Jurisdiction: Croatia
Funder: HRZZ
Funding stream: IP
Study programmeTitle: Graduate university studies in chemistry; specializations in: Research programme
Course: Research programme
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra kemije (magistar/magistra kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Embargo expiration date: 2022-07-02
Terms of useLicence In copyright icon
Created on2021-07-06 11:40:32