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master's thesis
Halogenska veza u solima halogenpiridina i heksacijanoželjezove(III) te heksacijanokobaltove(III) kiseline
Zagreb: University of Zagreb, Faculty of Science, 2021. urn:nbn:hr:217:277840
Jakupec, Nikola
University of Zagreb
Faculty of Science
Department of Chemistry

Institutional repository: Repository of the Faculty of Science

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Jakupec, N. (2021). Halogenska veza u solima halogenpiridina i heksacijanoželjezove(III) te heksacijanokobaltove(III) kiseline (Master's thesis). Zagreb: University of Zagreb, Faculty of Science. Retrieved from https://urn.nsk.hr/urn:nbn:hr:217:277840

Jakupec, Nikola. "Halogenska veza u solima halogenpiridina i heksacijanoželjezove(III) te heksacijanokobaltove(III) kiseline." Master's thesis, University of Zagreb, Faculty of Science, 2021. https://urn.nsk.hr/urn:nbn:hr:217:277840

Jakupec, Nikola. "Halogenska veza u solima halogenpiridina i heksacijanoželjezove(III) te heksacijanokobaltove(III) kiseline." Master's thesis, University of Zagreb, Faculty of Science, 2021. https://urn.nsk.hr/urn:nbn:hr:217:277840

Jakupec, N. (2021). 'Halogenska veza u solima halogenpiridina i heksacijanoželjezove(III) te heksacijanokobaltove(III) kiseline', Master's thesis, University of Zagreb, Faculty of Science, accessed 20 November 2024, https://urn.nsk.hr/urn:nbn:hr:217:277840

Jakupec N. Halogenska veza u solima halogenpiridina i heksacijanoželjezove(III) te heksacijanokobaltove(III) kiseline [Master's thesis]. Zagreb: University of Zagreb, Faculty of Science; 2021 [cited 2024 November 20] Available at: https://urn.nsk.hr/urn:nbn:hr:217:277840

N. Jakupec, "Halogenska veza u solima halogenpiridina i heksacijanoželjezove(III) te heksacijanokobaltove(III) kiseline", Master's thesis, University of Zagreb, Faculty of Science, Zagreb, 2021. Available at: https://urn.nsk.hr/urn:nbn:hr:217:277840

Metadata
TitleHalogenska veza u solima halogenpiridina i heksacijanoželjezove(III) te heksacijanokobaltove(III) kiseline
Title (english)Halogen bonding in halogenpiridinium salts of hexacyanoferrate(III) and hexacyanocobaltate(III) acid
AuthorNikola Jakupec
MentorVladimir Stilinović (mentor)
Committee memberVladimir Stilinović (predsjednik povjerenstva)
Committee memberGordan Horvat (član povjerenstva)
Committee memberIvan Kodrin (član povjerenstva)
Committee memberDominik Cinčić (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Science
(Department of Chemistry)
Zagreb
Defense date and country2021-07-12, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
U sklopu ovog diplomskog rada pripravljeno je pet soli halogenpiridina s heksacijanoželjezovom(III) kiselinom: (H5O2)(C6H6Cl)2[Fe(CN)6], (C6H6I)3[Fe(CN)6](CH3OH), (H5O2)(C6H6Cl)3[Fe(CN)6], (H5O2)(C6H6Br)2[Fe(CN)6], (H5O2)(C6H6I)2[Fe(CN)6]2(H2O)2. Također su pripremljene tri soli halogenpiridina s heksacijanokobaltovom(III) kiselinom: (H5O2)(C6H6Cl)2[Co(CN)6], (H5O2)(C6H6Br)2[Co(CN)6], (H5O2)(C6H6I)2[Co(CN)6](H2O)2. Korišteni su sljedeći halogenpiridini: 2-klorpiridin, 2-brompiridin, 2-jodpiridin, 3-klorpiridin, 3-brompiridin i 3-jodpiridin. Dobiveni spojevi analizirani su metodom difrakcije rentgenskog zračenja na monokristalnom uzorku u svrhu izučavanja kristalne strukture. Izučen je akceptorski potencijal cijanidnog liganda korištenih policijanometalata za halogensku vezu. Također je proučena supramolekulska kemija nastalih spojeva.
Abstract (english)
Five new salts of halogenpyridines and hexacyanoferrate(III) acid: (H5O2)(C6H6Cl)2[Fe(CN)6], (C6H6I)3[Fe(CN)6](CH3OH), (H5O2)(C6H6Cl)3[Fe(CN)6], (H5O2)(C6H6Br)2[Fe(CN)6], (H5O2)(C6H6I)2[Fe(CN)6]2(H2O)2, along with three salts of halogenpyridines and hexacyanocobaltate(III) acid: (H5O2)(C6H6Cl)2[Co(CN)6], (H5O2)(C6H6Br)2[Co(CN)6], (H5O2)(C6H6I)2[Co(CN)6](H2O)2 were prepared as a part of this master thesis. The following halogenpyridines were used for the preparation: 2-chloropyridine, 2-bromopyridine, 2-iodopyridine, 3-chloropyridine, 3-bromopyridine and 3-iodopyridine. The synthesized compounds were analyzed by single crystal X-ray diffraction to study the crystalline structure. The potential of cyano ligands of the polycyanometallates as halogen bond acceptors was also studied as well as the supramolecular chemistry of the prepared compounds.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:217:277840
Study programmeTitle: Graduate university studies in chemistry; specializations in: Research programme
Course: Research programme
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra kemije (magistar/magistra kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Embargo expiration date: 2023-07-12
Terms of useLicence In copyright icon
Created on2021-07-15 13:03:41