prikaz prve stranice dokumenta Role of metallic nanoclusters in catalysis for fuel cell feed gas purification and hydrogen storage
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doctoral thesis
Role of metallic nanoclusters in catalysis for fuel cell feed gas purification and hydrogen storage
Split: University of Split, Faculty of Science, 2016. urn:nbn:hr:166:827385
Krstić, Marjan
University of Split
Faculty of Science
Department of Physics

Institutional repository: Repository of Faculty of Science

Cite this document

Krstić, M. (2016). Role of metallic nanoclusters in catalysis for fuel cell feed gas purification and hydrogen storage (Doctoral thesis). Split: University of Split, Faculty of Science. Retrieved from https://urn.nsk.hr/urn:nbn:hr:166:827385

Krstić, Marjan. "Role of metallic nanoclusters in catalysis for fuel cell feed gas purification and hydrogen storage." Doctoral thesis, University of Split, Faculty of Science, 2016. https://urn.nsk.hr/urn:nbn:hr:166:827385

Krstić, Marjan. "Role of metallic nanoclusters in catalysis for fuel cell feed gas purification and hydrogen storage." Doctoral thesis, University of Split, Faculty of Science, 2016. https://urn.nsk.hr/urn:nbn:hr:166:827385

Krstić, M. (2016). 'Role of metallic nanoclusters in catalysis for fuel cell feed gas purification and hydrogen storage', Doctoral thesis, University of Split, Faculty of Science, accessed 15 November 2024, https://urn.nsk.hr/urn:nbn:hr:166:827385

Krstić M. Role of metallic nanoclusters in catalysis for fuel cell feed gas purification and hydrogen storage [Doctoral thesis]. Split: University of Split, Faculty of Science; 2016 [cited 2024 November 15] Available at: https://urn.nsk.hr/urn:nbn:hr:166:827385

M. Krstić, "Role of metallic nanoclusters in catalysis for fuel cell feed gas purification and hydrogen storage", Doctoral thesis, University of Split, Faculty of Science, Split, 2016. Available at: https://urn.nsk.hr/urn:nbn:hr:166:827385

Metadata
TitleRole of metallic nanoclusters in catalysis for fuel cell feed gas purification and hydrogen storage
Title (croatian)Uloga metalnih nanoklastera u katalizi za pročišćavanje pogonskog plina gorivnih ćelija i spremanje vodika
AuthorMarjan Krstić
MentorPaško Županović (mentor)
MentorVlasta Bonačić-Koutecky (komentor)
Committee memberAnte Bilušić (predsjednik povjerenstva)
Committee memberFranjo Sokolić (član povjerenstva)
Committee memberAnita Kriško (član povjerenstva)
GranterUniversity of Split
Faculty of Science
(Department of Physics)
Split
Defense date and country2016-12-19, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Physics
Universal decimal classification
(UDC)		577 - Biochemistry. Molecular biology. Biophysics
Abstract
Catalyticreactivity of the small transition and coinage metal nanoclusters have been theoretically studied in context of (1) advancing fuel cell technology by developing cost-effective techniques to improve quality of the feed gas as well as (2) safe storage and release of hydrogen in its gaseous state at room temperatures and pressures. In order to address the challenge concerning the improvement the quality of fuel cell feed gas reactions of small ruthenium cationic nanoclusters with CO and H2 has been performed. The origin of the selectivity and outstanding activity of small ruthenium nanoparticles in the catalytic CO methanation reaction has been identified. The second aim of this dissertation is to advance materials for hydrogen storage and their release technology. For this purpose a gas-phase study of fragmentation and catalytic activity of ligated coinage metal hydride nanoclusters has been performed. The theoretical findings based on density functional theory (DFT) are strongly supported by experimental results trough international cooperation. Within thesis we demonstrated that powerful combination of density functional theory and experimental investigations can contribute to intelligently developed new materials and procedures to overcome the challenges hampering worldwide application of fuel cells as ”green” technology of the future.
Abstract (croatian)
Katalitička reaktivnost malih nanoklastera prijelaznih metala teorijski je istraživana u kontekstu (1) unaprjeđenja tehnologije gorivnih članaka razvijajući jeftine tehnike poboljšanja kvalitete pogonskog plina kao i (2) sigurne pohrane i otpuštanja vodika u plinovitom stanju na atmosferskoj temperaturi i tlaku. Da bi riješili problem nedovoljne kvalitete pogonskog plina gorivnih članaka istraživale su se reakcije malih rutenijevih nanoklastera s CO i H2 . Izvor selektivnosti i izvrsne aktivnosti malih rutenijevih čestica u katalitičkoj CO metanacijskoj reakciji je identificiran. Drugi cilj ove disertacije ja unaprjeđivanje materijala za tehnologiju pohrane i otpuštanja vodika. U tu svrhu provela su se istraživanja fragmentacije i katalitičke aktivnosti ligandiranih metalnih hidridnih nanoklastera. Naša teorijska istraživanja bazirana na teoriji funkcionala gustoće su potvrđena eksperimentalnim rezultatima priznatih istraživačkih grupa kroz međunarodnu suradnju. Unutar ove teze demonstrirali smo da moćna kombinacija našeg teorijskog istraživanja potvrđena eksperimentalnim istraživanjima može doprinijeti inteligentnom razvoju novih materijala i procedura da bi se nadišli problemi koji sprječavaju široku primjenu gorivnih ćelija kao ”zelene” tehnologije budućnosti.
Keywords
Keywords (croatian)
Languageenglish
URN:NBNurn:nbn:hr:166:827385
Study programmeTitle: Postgraduate University Study of Biophysics
Study programme type: university
Study level: postgraduate
Academic / professional title: doktor/doktorica znanosti, područje prirodnih znanosti, polje fizika (doktor/doktorica znanosti, područje prirodnih znanosti, polje fizika)
Type of resourceText
Extent100 str. ; 30 cm
File originBorn digital
Access conditionsOpen access
Terms of useLicence In copyright icon
Created on2018-10-25 12:50:20