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doctoral thesis
Optical properties of noble metal nanocluster hybrids and their potential for biosensing
Split: University of Split, Faculty of Science, 2016. urn:nbn:hr:166:991726
Sanader Maršić, Željka
University of Split
Faculty of Science
Department of Physics

Institutional repository: Repository of Faculty of Science

Cite this document

Sanader Maršić, Ž. (2016). Optical properties of noble metal nanocluster hybrids and their potential for biosensing (Doctoral thesis). Split: University of Split, Faculty of Science. Retrieved from https://urn.nsk.hr/urn:nbn:hr:166:991726

Sanader Maršić, Željka. "Optical properties of noble metal nanocluster hybrids and their potential for biosensing." Doctoral thesis, University of Split, Faculty of Science, 2016. https://urn.nsk.hr/urn:nbn:hr:166:991726

Sanader Maršić, Željka. "Optical properties of noble metal nanocluster hybrids and their potential for biosensing." Doctoral thesis, University of Split, Faculty of Science, 2016. https://urn.nsk.hr/urn:nbn:hr:166:991726

Sanader Maršić, Ž. (2016). 'Optical properties of noble metal nanocluster hybrids and their potential for biosensing', Doctoral thesis, University of Split, Faculty of Science, accessed 11 July 2024, https://urn.nsk.hr/urn:nbn:hr:166:991726

Sanader Maršić Ž. Optical properties of noble metal nanocluster hybrids and their potential for biosensing [Doctoral thesis]. Split: University of Split, Faculty of Science; 2016 [cited 2024 July 11] Available at: https://urn.nsk.hr/urn:nbn:hr:166:991726

Ž. Sanader Maršić, "Optical properties of noble metal nanocluster hybrids and their potential for biosensing", Doctoral thesis, University of Split, Faculty of Science, Split, 2016. Available at: https://urn.nsk.hr/urn:nbn:hr:166:991726

Metadata
TitleOptical properties of noble metal nanocluster hybrids and their potential for biosensing
Title (croatian)Optička svojstva nanoklastera plemenitih metala unutar hibridnih sustava i njihova primjena u biosenzorici
AuthorŽeljka Sanader Maršić
MentorPaško Županović (mentor)
MentorVlasta Bonačić-Koutecky (komentor)
Committee memberAnte Bilušić (predsjednik povjerenstva)
Committee memberFranjo Sokolić (član povjerenstva)
Committee memberAnita Kriško (član povjerenstva)
GranterUniversity of Split
Faculty of Science
(Department of Physics)
Split
Defense date and country2016-12-19, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Physics
Universal decimal classification
(UDC)		577 - Biochemistry. Molecular biology. Biophysics
Abstract
Linear and nonlinear optical properties of functionalized forms of noble metal nanoclusters are addressed in this thesis. Noble metal nanoclusters belong to nonscalable regime in which each atom counts. They exhibit molecular like electronic transitions, due to quantum confinement effects, which are strongly influenced by structure. These systems have potential for applications in biosensing and bioimaging, based on their unique optical, electronic and structural properties, after being stabilized either by formation of hybrid systems of metal nanoclusters and biomolecules or protecting nanoclusters by ligands. Using density functional theory and its time dependent version interplay between electronic and structural properties in hybrid nanocluster-biomolecules and ligated clusters has been investigated in order to gain insight into origins of their unique optical properties. To understand optical properties of hybrid systems, silver cluster-histidine complexes, as well as nonlinear properties of ligated silver nanoclusters have been investigated theoretically, and compared with experimental results obtained by expert international collaborators. Within this thesis the concept has been worked out allowing to design systems with large two-photon cross sections which can serve for efficient imaging of tissues and cells.
Abstract (croatian)
U ovoj tezi su opisana linearna i nelinearna optička svojstva funkcioniziranih oblika nanoklastera plemenitih metala. Nanoklasteri plemenitih metala pripadaju neskalirajućim sustavima u kojima se svaki atom broji. Zbog efekata kvantnog zatočenja, imaju elektronske prijelaze slične onima u molekulama, na koje jako utječe struktura. Zbog svojih jedinstvenih optičkih, elektronskih i strukturnih svojstava, potencijalni su kandidati za primjene u biosenzorici i biooslikavanju, nakon što se stabiliziraju formiranjem hibridnih sustava s biomolekulama ili ih se zaštiti ligandima. U tezi je istraživan je odnos elektronskih i strukturnih svojstava u hibridnim sustavima biomolekula i metalnih klastera kao i u ligandiranim klasterima kako bi se razumio uzrok njihovih jedinstvenih optički svojstava, koristeći teoriju funkcionala gustoće i njenu vremenski ovisnu varijantu. Da bi se razumjela svojstva hibridnih sustava, teorijski su istraživani hibridni sustavi srebrenih klastera i histidina te nelinearna svojstva ligandiranih srebrnih klastera, i uspoređeni s eksperimentalnim rezultatima koje su napravili međunarodni suradnici. Razvijen je koncept koji bi mogao pomoći dizajniranju sustava s jakom dvo-fotonskom apsorpcijom koji bi služili za oslikavanje tkiva i stanica.
Keywords
Keywords (croatian)
Languageenglish
URN:NBNurn:nbn:hr:166:991726
Study programmeTitle: Postgraduate University Study of Biophysics
Study programme type: university
Study level: postgraduate
Academic / professional title: doktor/doktorica znanosti, područje prirodnih znanosti, polje fizika (doktor/doktorica znanosti, područje prirodnih znanosti, polje fizika)
Type of resourceText
Extent84 str. ; 30 cm
File originBorn digital
Access conditionsOpen access
Terms of useLicence In copyright icon
Created on2018-10-26 11:53:08