prikaz prve stranice dokumenta Chalcogen S∙∙∙S Bonding in Supramolecular Assemblies of Cadmium(II) Coordination Polymers with Pyridine-Based Ligands
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Scientific paper - Original scientific paper
Chalcogen S∙∙∙S Bonding in Supramolecular Assemblies of Cadmium(II) Coordination Polymers with Pyridine-Based Ligands
Crystals, 11 (2021), 6; 697. https://doi.org/10.3390/cryst11060697
Matijaković Mlinarić, Nives; Penić, Nikolina; Kukovec, Boris-Marko; Đaković, Marijana

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Matijaković Mlinarić, N., Penić, N., Kukovec, B. M. & Đaković, M. (2021). Chalcogen S∙∙∙S Bonding in Supramolecular Assemblies of Cadmium(II) Coordination Polymers with Pyridine-Based Ligands. Crystals, 11. (6). doi: 10.3390/cryst11060697

Matijaković Mlinarić, Nives, et al. "Chalcogen S∙∙∙S Bonding in Supramolecular Assemblies of Cadmium(II) Coordination Polymers with Pyridine-Based Ligands." Crystals, vol. 11, no. 6, 2021. https://doi.org/10.3390/cryst11060697

Matijaković Mlinarić, Nives, Nikolina Penić, Boris Marko Kukovec and Marijana Đaković. "Chalcogen S∙∙∙S Bonding in Supramolecular Assemblies of Cadmium(II) Coordination Polymers with Pyridine-Based Ligands." Crystals 11, no. 6 (2021). https://doi.org/10.3390/cryst11060697

Matijaković Mlinarić, N., et al. (2021) 'Chalcogen S∙∙∙S Bonding in Supramolecular Assemblies of Cadmium(II) Coordination Polymers with Pyridine-Based Ligands', Crystals, 11(6). doi: 10.3390/cryst11060697

Matijaković Mlinarić N, Penić N, Kukovec BM, Đaković M. Chalcogen S∙∙∙S Bonding in Supramolecular Assemblies of Cadmium(II) Coordination Polymers with Pyridine-Based Ligands. Crystals [Internet]. 2021 June 18 [cited 2024 November 29];11(6). doi: 10.3390/cryst11060697

N. Matijaković Mlinarić, N. Penić, B. M. Kukovec and M. Đaković, "Chalcogen S∙∙∙S Bonding in Supramolecular Assemblies of Cadmium(II) Coordination Polymers with Pyridine-Based Ligands", Crystals, vol. 11, no. 6, June 2021. [Online]. Available at: https://urn.nsk.hr/urn:nbn:hr:217:477983. [Accessed: 29 November 2024]

Metadata
Title (english)Chalcogen S∙∙∙S Bonding in Supramolecular Assemblies of Cadmium(II) Coordination Polymers with Pyridine-Based Ligands
AuthorNives Matijaković Mlinarić
AuthorNikolina Penić
AuthorBoris-Marko Kukovec
AuthorMarijana Đaković
Author's institutionUniversity of Zagreb
Faculty of Science
(Department of Physics)
Author's institutionUniversity of Zagreb
Faculty of Science
(Department of Chemistry)
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract (english)
Two cadmium(II) coordination polymers, with thiocyanate and pyridine-based ligands e.g., 3-acetamidopyridine (3-Acpy) and niazid (nicotinic acid hydrazide, nia), namely one-dimensional {[Cd(SCN)2 (3-Acpy)]}n (1) and two-dimensional {[Cd(SCN)2 (nia)]}n (2), are prepared in the mixture of water and ethanol. The adjacent cadmium(II) ions in 1 are bridged by two N,S-thiocyanate ions and an N,O-bridging 3-Acpy molecule, forming infinite one-dimensional polymeric chains, which are assembled by the intermolecular N–H···S hydrogen bonds in one direction and by the intermolecular S···S chalcogen bonds in another direction. Within the coordination network of 2, the adjacent cadmium(II) ions are bridged by N,S-thiocyanate ions in one direction and by N,O,N’-chelating and bridging nia molecules in another direction. The coordination networks of 2 are assembled by the intermolecular N–H···S and N–H···N hydrogen bonds and S···S chalcogen bonds. Being the only supramolecular interactions responsible for assembling the polymer chains of 1 in the particular direction, the chalcogen S···S bonds are more significant in the structure of 1, whilst the chalcogen S···S bonds which act in cooperation with the N–H···S and N–H···N hydrogen bonds are of less significance in the structure of 2.
Keywords (english)
Languageenglish
Publication typeScientific paper - Original scientific paper
Publication statusPublished
Peer reviewPeer review - international
Publication versionPublished version
Journal titleCrystals
Numberingvol. 11, no. 6, 697
e-ISSN2073-4352
DOIhttps://doi.org/10.3390/cryst11060697
URN:NBNurn:nbn:hr:217:477983
Publication2021-06-18
ProjectNumber: IP-2019-04-1242
Title (croatian): Od oblika do funkcije: Fleksibilni kristalni materijali s kontroliranim mehaničkim odzivom
Title (english): From form to function: Mechanically flexible crystalline materials with controllable responses
Acronym: FlexibleCrystals
Leader: Marijana Đaković
Jurisdiction: Croatia
Funding stream: IP
Document URLhttps://www.mdpi.com/2073-4352/11/6/697
Type of resourceText
Access conditionsOpen access
Terms of useLicence Attribution 4.0 International (CC BY 4.0) icon
Public note© 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https:// creativecommons.org/licenses/by/ 4.0/. Received: 31 May 2021; Accepted: 14 June 2021; Published: 18 June 2021.
Created on2023-08-06 14:25:27