prikaz prve stranice dokumenta Chalcogen S∙∙∙S Bonding in Supramolecular Assemblies of Cadmium(II) Coordination Polymers with Pyridine-Based Ligands
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Chalcogen S∙∙∙S Bonding in Supramolecular Assemblies of Cadmium(II) Coordination Polymers with Pyridine-Based Ligands
Crystals, 11 (2021), 6; 697. https://doi.org/10.3390/cryst11060697
Matijaković Mlinarić, Nives; Penić, Nikolina; Kukovec, Boris-Marko; Đaković, Marijana

Institucijski repozitorij: Repozitorij Prirodoslovno-matematičkog fakulteta

Citirajte ovaj rad

Matijaković Mlinarić, N., Penić, N., Kukovec, B. M. i Đaković, M. (2021). Chalcogen S∙∙∙S Bonding in Supramolecular Assemblies of Cadmium(II) Coordination Polymers with Pyridine-Based Ligands. Crystals, 11. (6). doi: 10.3390/cryst11060697

Matijaković Mlinarić, Nives, et al. "Chalcogen S∙∙∙S Bonding in Supramolecular Assemblies of Cadmium(II) Coordination Polymers with Pyridine-Based Ligands." Crystals, vol. 11, br. 6, 2021. https://doi.org/10.3390/cryst11060697

Matijaković Mlinarić, Nives, Nikolina Penić, Boris Marko Kukovec i Marijana Đaković. "Chalcogen S∙∙∙S Bonding in Supramolecular Assemblies of Cadmium(II) Coordination Polymers with Pyridine-Based Ligands." Crystals 11, br. 6 (2021). https://doi.org/10.3390/cryst11060697

Matijaković Mlinarić, N., et al. (2021) 'Chalcogen S∙∙∙S Bonding in Supramolecular Assemblies of Cadmium(II) Coordination Polymers with Pyridine-Based Ligands', Crystals, 11(6). doi: 10.3390/cryst11060697

Matijaković Mlinarić N, Penić N, Kukovec BM, Đaković M. Chalcogen S∙∙∙S Bonding in Supramolecular Assemblies of Cadmium(II) Coordination Polymers with Pyridine-Based Ligands. Crystals [Internet]. 18.06.2021. [pristupljeno 27.04.2024.];11(6). doi: 10.3390/cryst11060697

N. Matijaković Mlinarić, N. Penić, B. M. Kukovec i M. Đaković, "Chalcogen S∙∙∙S Bonding in Supramolecular Assemblies of Cadmium(II) Coordination Polymers with Pyridine-Based Ligands", Crystals, vol. 11, br. 6, Lipanj 2021. [Online]. Dostupno na: https://urn.nsk.hr/urn:nbn:hr:217:477983. [Citirano: 27.04.2024.]

Za citiranje koristite ovu mrežnu adresu: https://urn.nsk.hr/urn:nbn:hr:217:477983
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Naslov (engleski)Chalcogen S∙∙∙S Bonding in Supramolecular Assemblies of Cadmium(II) Coordination Polymers with Pyridine-Based Ligands
AutorNives Matijaković Mlinarić
AutorNikolina Penić
AutorBoris-Marko Kukovec
AutorMarijana Đaković
Autorova ustanovaSveučilište u Zagrebu
Prirodoslovno-matematički fakultet
(Fizički odsjek)
Autorova ustanovaSveučilište u Zagrebu
Prirodoslovno-matematički fakultet
(Kemijski odsjek)
Znanstveno / umjetničko
područje, polje i grana		PRIRODNE ZNANOSTI
Kemija
Sažetak (engleski)
Two cadmium(II) coordination polymers, with thiocyanate and pyridine-based ligands e.g., 3-acetamidopyridine (3-Acpy) and niazid (nicotinic acid hydrazide, nia), namely one-dimensional {[Cd(SCN)2 (3-Acpy)]}n (1) and two-dimensional {[Cd(SCN)2 (nia)]}n (2), are prepared in the mixture of water and ethanol. The adjacent cadmium(II) ions in 1 are bridged by two N,S-thiocyanate ions and an N,O-bridging 3-Acpy molecule, forming infinite one-dimensional polymeric chains, which are assembled by the intermolecular N–H···S hydrogen bonds in one direction and by the intermolecular S···S chalcogen bonds in another direction. Within the coordination network of 2, the adjacent cadmium(II) ions are bridged by N,S-thiocyanate ions in one direction and by N,O,N’-chelating and bridging nia molecules in another direction. The coordination networks of 2 are assembled by the intermolecular N–H···S and N–H···N hydrogen bonds and S···S chalcogen bonds. Being the only supramolecular interactions responsible for assembling the polymer chains of 1 in the particular direction, the chalcogen S···S bonds are more significant in the structure of 1, whilst the chalcogen S···S bonds which act in cooperation with the N–H···S and N–H···N hydrogen bonds are of less significance in the structure of 2.
Ključne riječi (engleski)
Jezikengleski
Vrsta publikacijeZnanstveni rad - Izvorni znanstveni rad
Status objaveObjavljen
Vrsta recenzijeRecenziran - međunarodna recenzija
Verzija publikacijeObjavljena verzija rada (izdavačev PDF)
Naslov časopisaCrystals
Brojčani podacivol. 11, br. 6, 697
e-ISSN2073-4352
DOIhttps://doi.org/10.3390/cryst11060697
URN:NBNurn:nbn:hr:217:477983
Datum objave publikacije2021-06-18
ProjektŠifra: IP-2019-04-1242
Naziv (hrvatski): Od oblika do funkcije: Fleksibilni kristalni materijali s kontroliranim mehaničkim odzivom
Naziv (engleski): From form to function: Mechanically flexible crystalline materials with controllable responses
Kratica: FlexibleCrystals
Voditelj: Marijana Đaković
Pravna nadležnost: Hrvatska
Financijer: HRZZ
Linija financiranja: IP
URL dokumentahttps://www.mdpi.com/2073-4352/11/6/697
Vrsta resursaTekst
Prava pristupaOtvoreni pristup
Uvjeti korištenjaIkona licence Imenovanje 4.0 međunarodna (CC BY 4.0)
Javna napomena© 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https:// creativecommons.org/licenses/by/ 4.0/. Received: 31 May 2021; Accepted: 14 June 2021; Published: 18 June 2021.
Datum i vrijeme pohrane2023-08-06 14:25:27