prikaz prve stranice dokumenta Structure-Related Evolution of Magnetic Order in Anisidinium Tetrachlorocuprates(II)
  Download
PDF 5.18 MB
Scientific paper - Original scientific paper
Structure-Related Evolution of Magnetic Order in Anisidinium Tetrachlorocuprates(II)
Crystal Growth & Design, 23 (2023), 6; 4262-4272. https://doi.org/10.1021/acs.cgd.3c00066
Topić, Edi; Šenjug, Pavla; Barišić, Dario; Lončarić, Ivor; Pajić, Damir; Rubčić, Mirta

Institutional repository: Repository of the Faculty of Science

Cite this document

Topić, E., Šenjug, P., Barišić, D., Lončarić, I., Pajić, D. & Rubčić, M. (2023). Structure-Related Evolution of Magnetic Order in Anisidinium Tetrachlorocuprates(II). Crystal Growth & Design, 23. (6), 4262-4272. doi: 10.1021/acs.cgd.3c00066

Topić, Edi, et al. "Structure-Related Evolution of Magnetic Order in Anisidinium Tetrachlorocuprates(II)." Crystal Growth & Design, vol. 23, no. 6, 2023, pp. 4262-4272. https://doi.org/10.1021/acs.cgd.3c00066

Topić, Edi, Pavla Šenjug, Dario Barišić, Ivor Lončarić, Damir Pajić and Mirta Rubčić. "Structure-Related Evolution of Magnetic Order in Anisidinium Tetrachlorocuprates(II)." Crystal Growth & Design 23, no. 6 (2023): 4262-4272. https://doi.org/10.1021/acs.cgd.3c00066

Topić, E., et al. (2023) 'Structure-Related Evolution of Magnetic Order in Anisidinium Tetrachlorocuprates(II)', Crystal Growth & Design, 23(6), pp. 4262-4272. doi: 10.1021/acs.cgd.3c00066

Topić E, Šenjug P, Barišić D, Lončarić I, Pajić D, Rubčić M. Structure-Related Evolution of Magnetic Order in Anisidinium Tetrachlorocuprates(II). Crystal Growth & Design [Internet]. 2023 May 09 [cited 2024 November 18];23(6):4262-4272. doi: 10.1021/acs.cgd.3c00066

E. Topić, P. Šenjug, D. Barišić, I. Lončarić, D. Pajić and M. Rubčić, "Structure-Related Evolution of Magnetic Order in Anisidinium Tetrachlorocuprates(II)", Crystal Growth & Design, vol. 23, no. 6, pp. 4262-4272, May 2023. [Online]. Available at: https://urn.nsk.hr/urn:nbn:hr:217:846122. [Accessed: 18 November 2024]

Metadata
Title (english)Structure-Related Evolution of Magnetic Order in Anisidinium Tetrachlorocuprates(II)
AuthorEdi Topić
AuthorPavla Šenjug
AuthorDario Barišić
AuthorIvor Lončarić
AuthorDamir Pajić
AuthorMirta Rubčić
Author's institutionUniversity of Zagreb
Faculty of Science
(Department of Physics)
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Physics
Abstract (english)
Tetrachlorocuprate(II) hybrids of the three anisidine isomers (ortho-, meta-, and para-, or 2-, 3-, and 4-methoxyaniline, respectively) were prepared and studied in the solid state via X-ray diffraction and magnetization measurements. Depending on the position of the methoxy group of the organic cation, and subsequently, the overall cation geometry, a layered, defective layered, and the structure comprising discrete tetrachlorocuprate(II) units were obtained for the para-, meta-, and ortho-anisidinium hybrids, respectively. In the case of layered and defective layered structures, this affords quasi-2D-layered magnets, demonstrating a complex interplay of strong and weak magnetic interactions that lead to the long-range ferromagnetic (FM) order. In the case of the structure with discrete CuCl42– ions, a peculiar antiferromagnetic (AFM) behavior was revealed. The structural and electronic origins of magnetism are discussed in detail. To supplement it, the method for calculation of dimensionality of the inorganic framework as a function of interaction length was developed. The same was used to discriminate between n-dimensional and “almost” n-dimensional frameworks, to estimate the organic cation geometry limits for layered halometallates, and to provide additional reasoning behind the observed relation between cation geometry and framework dimensionality, as well as their relation to differences in magnetic behavior.
Keywords (english)
Languageenglish
Publication typeScientific paper - Original scientific paper
Publication statusPublished
Peer reviewPeer review - international
Publication versionPublished version
Journal titleCrystal Growth & Design
Numberingvol. 23, no. 6, pp. 4262-4272
p-ISSN1528-7483
e-ISSN1528-7505
DOIhttps://doi.org/10.1021/acs.cgd.3c00066
URN:NBNurn:nbn:hr:217:846122
Publication2023-05-09
ProjectNumber: UIP-2014-09-8276
Title (croatian): Magnetoelektrični multiferoični sustavi
Title (english): Multiferroic and magneto-electric systems
Acronym: FerMaEl
Leader: Damir Pajić
Jurisdiction: Croatia
Funding stream: Installation Research Projects
Document URLhttps://pubs.acs.org/doi/10.1021/acs.cgd.3c00066
Type of resourceText
Access conditionsOpen access
Terms of useLicence Attribution 4.0 International (CC BY 4.0) icon
Public noteCopyright © 2023 The Authors. Published by American Chemical Society. This publication is licensed under CC-BY 4.0. Received: January 18, 2023Revised: April 26, 2023Published: May 9, 2023.
Created on2024-07-23 08:23:36