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Structure-Related Evolution of Magnetic Order in Anisidinium Tetrachlorocuprates(II)
Crystal Growth & Design, 23 (2023), 6; 4262-4272. https://doi.org/10.1021/acs.cgd.3c00066
Topić, Edi; Šenjug, Pavla; Barišić, Dario; Lončarić, Ivor; Pajić, Damir; Rubčić, Mirta

Institucijski repozitorij: Repozitorij Prirodoslovno-matematičkog fakulteta

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Topić, E., Šenjug, P., Barišić, D., Lončarić, I., Pajić, D. i Rubčić, M. (2023). Structure-Related Evolution of Magnetic Order in Anisidinium Tetrachlorocuprates(II). Crystal Growth & Design, 23. (6), 4262-4272. doi: 10.1021/acs.cgd.3c00066

Topić, Edi, et al. "Structure-Related Evolution of Magnetic Order in Anisidinium Tetrachlorocuprates(II)." Crystal Growth & Design, vol. 23, br. 6, 2023, str. 4262-4272. https://doi.org/10.1021/acs.cgd.3c00066

Topić, Edi, Pavla Šenjug, Dario Barišić, Ivor Lončarić, Damir Pajić i Mirta Rubčić. "Structure-Related Evolution of Magnetic Order in Anisidinium Tetrachlorocuprates(II)." Crystal Growth & Design 23, br. 6 (2023): 4262-4272. https://doi.org/10.1021/acs.cgd.3c00066

Topić, E., et al. (2023) 'Structure-Related Evolution of Magnetic Order in Anisidinium Tetrachlorocuprates(II)', Crystal Growth & Design, 23(6), str. 4262-4272. doi: 10.1021/acs.cgd.3c00066

Topić E, Šenjug P, Barišić D, Lončarić I, Pajić D, Rubčić M. Structure-Related Evolution of Magnetic Order in Anisidinium Tetrachlorocuprates(II). Crystal Growth & Design [Internet]. 09.05.2023. [pristupljeno 08.11.2024.];23(6):4262-4272. doi: 10.1021/acs.cgd.3c00066

E. Topić, P. Šenjug, D. Barišić, I. Lončarić, D. Pajić i M. Rubčić, "Structure-Related Evolution of Magnetic Order in Anisidinium Tetrachlorocuprates(II)", Crystal Growth & Design, vol. 23, br. 6, str. 4262-4272, Svibanj 2023. [Online]. Dostupno na: https://urn.nsk.hr/urn:nbn:hr:217:846122. [Citirano: 08.11.2024.]

Za citiranje koristite ovu mrežnu adresu: https://urn.nsk.hr/urn:nbn:hr:217:846122
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Naslov (engleski)Structure-Related Evolution of Magnetic Order in Anisidinium Tetrachlorocuprates(II)
AutorEdi Topić
AutorPavla Šenjug
AutorDario Barišić
AutorIvor Lončarić
AutorDamir Pajić
AutorMirta Rubčić
Autorova ustanovaSveučilište u Zagrebu
Prirodoslovno-matematički fakultet
(Fizički odsjek)
Znanstveno / umjetničko
područje, polje i grana		PRIRODNE ZNANOSTI
Fizika
Sažetak (engleski)
Tetrachlorocuprate(II) hybrids of the three anisidine isomers (ortho-, meta-, and para-, or 2-, 3-, and 4-methoxyaniline, respectively) were prepared and studied in the solid state via X-ray diffraction and magnetization measurements. Depending on the position of the methoxy group of the organic cation, and subsequently, the overall cation geometry, a layered, defective layered, and the structure comprising discrete tetrachlorocuprate(II) units were obtained for the para-, meta-, and ortho-anisidinium hybrids, respectively. In the case of layered and defective layered structures, this affords quasi-2D-layered magnets, demonstrating a complex interplay of strong and weak magnetic interactions that lead to the long-range ferromagnetic (FM) order. In the case of the structure with discrete CuCl42– ions, a peculiar antiferromagnetic (AFM) behavior was revealed. The structural and electronic origins of magnetism are discussed in detail. To supplement it, the method for calculation of dimensionality of the inorganic framework as a function of interaction length was developed. The same was used to discriminate between n-dimensional and “almost” n-dimensional frameworks, to estimate the organic cation geometry limits for layered halometallates, and to provide additional reasoning behind the observed relation between cation geometry and framework dimensionality, as well as their relation to differences in magnetic behavior.
Ključne riječi (engleski)
Jezikengleski
Vrsta publikacijeZnanstveni rad - Izvorni znanstveni rad
Status objaveObjavljen
Vrsta recenzijeRecenziran - međunarodna recenzija
Verzija publikacijeObjavljena verzija rada (izdavačev PDF)
Naslov časopisaCrystal Growth & Design
Brojčani podacivol. 23, br. 6, str. 4262-4272
p-ISSN1528-7483
e-ISSN1528-7505
DOIhttps://doi.org/10.1021/acs.cgd.3c00066
URN:NBNurn:nbn:hr:217:846122
Datum objave publikacije2023-05-09
ProjektŠifra: UIP-2014-09-8276
Naziv (hrvatski): Magnetoelektrični multiferoični sustavi
Naziv (engleski): Multiferroic and magneto-electric systems
Kratica: FerMaEl
Voditelj: Damir Pajić
Pravna nadležnost: Hrvatska
Financijer: Hrvatska zaklada za znanost
Linija financiranja: Installation Research Projects
URL dokumentahttps://pubs.acs.org/doi/10.1021/acs.cgd.3c00066
Vrsta resursaTekst
Prava pristupaOtvoreni pristup
Uvjeti korištenjaIkona licence Imenovanje 4.0 međunarodna (CC BY 4.0)
Javna napomenaCopyright © 2023 The Authors. Published by American Chemical Society. This publication is licensed under CC-BY 4.0. Received: January 18, 2023Revised: April 26, 2023Published: May 9, 2023.
Datum i vrijeme pohrane2024-07-23 08:23:36