prikaz prve stranice dokumenta A comparison of carbon-carbon double bond and cyclopropane as neighboring groups. Solvolysis rates of 1-aryl-4-cyclopropylbutyl chlorides
  Preuzmi
PDF 6.64 MB
Znanstveni rad - Izvorni znanstveni rad
A comparison of carbon-carbon double bond and cyclopropane as neighboring groups. Solvolysis rates of 1-aryl-4-cyclopropylbutyl chlorides
Croatica Chemica Acta, 54 (1981), 2; 203-209. urn:nbn:hr:163:775224
Ostović, D.; Kronja, O.; Borčić, S.

Institucijski repozitorij: Repozitorij Farmaceutsko-biokemijskog fakulteta Sveučilišta u Zagrebu

Citirajte ovaj rad

Ostović, D., Kronja, O. i Borčić, S. (1981). A comparison of carbon-carbon double bond and cyclopropane as neighboring groups. Solvolysis rates of 1-aryl-4-cyclopropylbutyl chlorides. Croatica Chemica Acta, 54. (2), 203-209. Preuzeto s https://urn.nsk.hr/urn:nbn:hr:163:775224

Ostović, D., et al. "A comparison of carbon-carbon double bond and cyclopropane as neighboring groups. Solvolysis rates of 1-aryl-4-cyclopropylbutyl chlorides." Croatica Chemica Acta, vol. 54, br. 2, 1981, str. 203-209. https://urn.nsk.hr/urn:nbn:hr:163:775224

Ostović, D., O. Kronja i S. Borčić. "A comparison of carbon-carbon double bond and cyclopropane as neighboring groups. Solvolysis rates of 1-aryl-4-cyclopropylbutyl chlorides." Croatica Chemica Acta 54, br. 2 (1981): 203-209. https://urn.nsk.hr/urn:nbn:hr:163:775224

Ostović, D., Kronja, O. i Borčić, S. (1981) 'A comparison of carbon-carbon double bond and cyclopropane as neighboring groups. Solvolysis rates of 1-aryl-4-cyclopropylbutyl chlorides', Croatica Chemica Acta, 54(2), str. 203-209. Preuzeto s: https://urn.nsk.hr/urn:nbn:hr:163:775224 (Datum pristupa: 28.11.2024.)

Ostović D, Kronja O, Borčić S. A comparison of carbon-carbon double bond and cyclopropane as neighboring groups. Solvolysis rates of 1-aryl-4-cyclopropylbutyl chlorides. Croatica Chemica Acta [Internet]. 1981. [pristupljeno 28.11.2024.];54(2):203-209. Dostupno na: https://urn.nsk.hr/urn:nbn:hr:163:775224

D. Ostović, O. Kronja i S. Borčić, "A comparison of carbon-carbon double bond and cyclopropane as neighboring groups. Solvolysis rates of 1-aryl-4-cyclopropylbutyl chlorides", Croatica Chemica Acta, vol. 54, br. 2, str. 203-209, 1981. [Online]. Dostupno na: https://urn.nsk.hr/urn:nbn:hr:163:775224. [Citirano: 28.11.2024.]

Za citiranje koristite ovu mrežnu adresu: https://urn.nsk.hr/urn:nbn:hr:163:775224
Podaci o radu
Naslov (engleski)A comparison of carbon-carbon double bond and cyclopropane as neighboring groups. Solvolysis rates of 1-aryl-4-cyclopropylbutyl chlorides
AutorD. Ostović
AutorO. Kronja
AutorS. Borčić
Autorova ustanovaSveučilište u Zagrebu
Farmaceutsko-biokemijski fakultet
(Zavod za organsku kemiju)
Znanstveno / umjetničko
područje, polje i grana		PRIRODNE ZNANOSTI
Kemija
Organska kemija
Sažetak (engleski)
1-Phenyl-4-cyclopropylbutyl chloride 13a and 1-m-bromophenyl- 4-cyclopropylbutyl chloride 13b were prepared and their solvolysis rates measured. As with corresponding 1-aryl-5-hexenyl chlorides 9, no reaction rate increases were observed. In contrast, 1-aryl-5-methyl-5-hexenyl chlorides 10 and 1-aryl-5-heptenyl chlorides 11 which are isomeric to 13 solvolyze with significant anchimeric assistance of the methyl-substituted aliphatic double bond. This failure of the cyclopropane ring to act as a neighboring group is rationalized in terms of possible charge delocalization in the reaction transition state arising from 13 and from 10 or 11.
Jezikengleski
Vrsta publikacijeZnanstveni rad - Izvorni znanstveni rad
Status objaveObjavljen
Vrsta recenzijeRecenziran - međunarodna recenzija
Verzija publikacijeObjavljena verzija rada (izdavačev PDF)
Naslov časopisaCroatica Chemica Acta
Brojčani podacivol. 54, br. 2, str. 203-209
p-ISSN0011-1643
e-ISSN1334-417X
URN:NBNurn:nbn:hr:163:775224
Datum objave publikacije1981
URL dokumentahttps://hrcak.srce.hr/194337
Vrsta resursaTekst
Prava pristupaOtvoreni pristup
Uvjeti korištenjaIkona licence Zaštićeno autorskim pravom.
Datum i vrijeme pohrane2020-05-05 14:40:46